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Issue 13, 2000
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A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands

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Abstract

The five-coordinate bis(salicylaldiminato)chromium(III) complex [3,5-(t-Bu)2(O)C6H2CHN(2,6-i-Pr2C6H3)]2CrCl (2) reacts with triethylaluminium in THF at room temperature to give the air sensitive ethyl species [3,5-(t-Bu)2(O)C6H2CHN(2,6-i-Pr2C6H3)]2CrEt (3); in the presence of aluminium activators, 2 and 3 are moderately active ethylene polymerisation catalysts.

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Publication details

The article was received on 03 Apr 2000, accepted on 22 May 2000 and first published on 14 Jun 2000


Article type: Paper
DOI: 10.1039/B002631J
Citation: J. Chem. Soc., Dalton Trans., 2000, 1969-1971
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    A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands

    V. C. Gibson, S. Mastroianni, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White and D. J. Williams, J. Chem. Soc., Dalton Trans., 2000, 1969
    DOI: 10.1039/B002631J

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