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Issue 10, 2000
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Synthesis and characterisation of novel layered compounds, Cs2MP3O10 (M = Al or Ga), containing triphosphate groups

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Abstract

The compounds Cs2AlP3O10 and Cs2GaP3O10 have been synthesized by solid state reactions and structurally characterised by single crystal X-ray diffraction. They are two dimensional compounds possessing corrugated [MP3O10]2− anionic layers interleaved with Cs+ ions. The layers are built from MO6 octahedra and bent triphosphate groups. Solid state NMR studies corroborate the presence of crystallographically distinct phosphorus atoms of triphosphate groups.

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Publication details

The article was received on 13 Dec 1999, accepted on 20 Mar 2000 and first published on 26 Apr 2000


Article type: Paper
DOI: 10.1039/A909753H
Citation: J. Chem. Soc., Dalton Trans., 2000,0, 1605-1608
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    Synthesis and characterisation of novel layered compounds, Cs2MP3O10 (M = Al or Ga), containing triphosphate groups

    R. N. Devi and K. Vidyasagar, J. Chem. Soc., Dalton Trans., 2000, 0, 1605
    DOI: 10.1039/A909753H

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