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Issue 4, 2000
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Phosphine and phosphido indium hydride complexes and their use in inorganic synthesis

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Abstract

Reaction of PR3, R = cyclohexyl (Cy), cyclopentyl (Cyp) or phenyl, with [InH3(NMe3)] affords the 1∶1 indium trihydride complexes, [InH3(PR3)]. The stabilities and spectroscopic properties of these complexes are described in terms of the phosphine ligands’ steric bulk and nucleophilicity. Reaction of two equivalents of PCy3 with [InH3(NMe3)] yields the complex [InH3(PCy3)2] which has been characterised by X-ray crystallography. The first phosphido–indium hydride complex, [{InH2(PCy2)}3], has been prepared by a novel synthetic route which involves treatment of [InH3(NMe3)] with LiPCy2. Its crystal structure shows it to exist as a cyclic trimer in the solid state. The complex, [InH3(PCy3)] has been used to prepare a range of monomeric indium chalcogenolato complexes, [In(EPh)3(PCy3)], E = S, Se or Te, all of which have been structurally characterised.

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Publication details

The article was received on 21 Oct 1999, accepted on 22 Dec 1999 and first published on 27 Jan 2000


Article type: Paper
DOI: 10.1039/A908418E
Citation: J. Chem. Soc., Dalton Trans., 2000, 545-550
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    Phosphine and phosphido indium hydride complexes and their use in inorganic synthesis

    M. L. Cole, D. E. Hibbs, C. Jones and N. A. Smithies, J. Chem. Soc., Dalton Trans., 2000, 545
    DOI: 10.1039/A908418E

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