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Issue 32, 2000

Triple hydrogen bond directed crystal engineering of metal assembled complexes: the effect of a bifunctional ligand on supramolecular structure

Yuichi Sugiyama,a  Keiichi Adachi,a  Satoshi Kawata,*a  Hitoshi Kumagai,b  Katsuya Inoue,b  Motomi Katadac  and  Susumu Kitagawad 
Author affiliations

* Corresponding authors

a Department of Chemistry, Shizuoka University, 836 Ohya, Shizuoka, Japan
E-mail: scskawa@ipc.shizuoka.ac.jp

b Institute for Molecular Science, Myodaiji, Okazaki, Japan

c Department of Chemistry, Tokyo Metropolitan University, Minami Ohsawa, Hachiouji, Tokyo, Japan

d Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Sakyo-ku, Kyoto, Japan

Abstract

The crystal structures of compounds [Hmel]2[M(tdpd)2(OH2)2]·2H2O (M = Ni2+, Co2+; Hmel+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile) are reported; the metal complex supramolecular structures can be rationally designed via hydrogen bonding interactions.

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Publication details

The article was received on 02 Oct 2000 and accepted on 30 Oct 2000


Article type: Paper
DOI: 10.1039/B007939L
Citation: CrystEngComm, 2000,2, 174-176
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    Triple hydrogen bond directed crystal engineering of metal assembled complexes: the effect of a bifunctional ligand on supramolecular structure

    Y. Sugiyama, K. Adachi, S. Kawata, H. Kumagai, K. Inoue, M. Katada and S. Kitagawa, CrystEngComm, 2000, 2, 174
    DOI: 10.1039/B007939L

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