Issue 23, 2000

The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

Abstract

The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conversion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl complex is achieved using triphenylphosphine as reductant.

Supplementary files

Article information

Article type
Communication
Submitted
18 Aug 2000
Accepted
17 Oct 2000
First published
08 Nov 2000

Chem. Commun., 2000, 2301-2302

The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

L. Cheng, D. R. Powell, M. A. Khan and G. B. Richter-Addo, Chem. Commun., 2000, 2301 DOI: 10.1039/B006775J

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