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Issue 21, 2000
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Metallacyclophanes formed by a tetrapyrazolyl ligand and copper(II) cation

Abdelaziz Jouaiti,a  Marielle Loï,a  Mir Wais Hosseini*a  and  André De Ciana 
Author affiliations

* Corresponding authors

a Laboratoire de Chimie de Coordinaiton Organique, Université Louis Pasteur, UMR CNRS 7513., Strasbourg, France
E-mail: hasseini@chimie.u-strasbg.fr

Abstract

Using a tetrakis(pyrazolyl)benzene ligand and CuCl2 or Cu(CF3SO3)2 salts, binuclear metallamacrocycles of cyclophane type have been exclusively obtained; structural characterisation by X-ray on single-crystal reveals that in both cases, chloride or triflate anions are coordinated to Cu metal centres adopting a square pyramial coordination geometry.

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Publication details

The article was received on 15 Aug 2000, accepted on 18 Sep 2000 and first published on 19 Oct 2000


Article type: Communication
DOI: 10.1039/B006665F
Citation: Chem. Commun., 2000,0, 2085-2086
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    Metallacyclophanes formed by a tetrapyrazolyl ligand and copper(II) cation

    A. Jouaiti, M. Loï, M. W. Hosseini and A. De Cian, Chem. Commun., 2000, 0, 2085
    DOI: 10.1039/B006665F

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