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Issue 19, 2000
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Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines

Chan Sik Cho,a  Byoung Ho Oh,a  Joon Seok Kim,a  Tae-Jeong Kima  and  Sang Chul Shim*a 
Author affiliations

* Corresponding authors

a Department of Industrial Chemistry, College of Engineering, Kyungpook National University, Taegu, Korea.
E-mail: scshim@kyungpook.ac.kr

Abstract

Anilines react with an array of trialkylamines in the presence of a catalytic amount of RuCl3·nH2O and bis(diphenylphosphino)methane together with SnCl2·2H2O and hex-1-ene as hydrogen acceptor in dioxane at 180 °C to afford the corresponding 2,3-disubstituted quinolines in moderate to good yields.

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Publication details

The article was received on 24 Jul 2000, accepted on 25 Aug 2000 and first published on 18 Sep 2000


Article type: Communication
DOI: 10.1039/B005966H
Citation: Chem. Commun., 2000,0, 1885-1886
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    Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines

    C. S. Cho, B. H. Oh, J. S. Kim, T. Kim and S. C. Shim, Chem. Commun., 2000, 0, 1885
    DOI: 10.1039/B005966H

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