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Issue 20, 2000
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Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue

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Abstract

The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.

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Publication details

The article was received on 12 Jul 2000, accepted on 06 Sep 2000 and first published on 27 Sep 2000


Article type: Communication
DOI: 10.1039/B005686N
Citation: Chem. Commun., 2000, 1991-1992
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    Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(I) carbene analogue

    N. J. Hardman, B. E. Eichler and P. P. Power, Chem. Commun., 2000, 1991
    DOI: 10.1039/B005686N

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