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Issue 22, 2000
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Synthesis and crystal structure of [IBa(OBut)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium

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Abstract

The reaction of [BaI2(thf)5] with LiOBut in THF in the presence of hydroxide yields a volatile mixed alkali and alkaine earth metal cluster with an unusually low coordination number for the alkaline earth cation; due to the presence of the alkoxide groups, the cluster is volatile at temperatures below 200 °C.

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Publication details

The article was received on 12 Jul 2000, accepted on 05 Oct 2000 and first published on 25 Oct 2000


Article type: Communication
DOI: 10.1039/B005638N
Citation: Chem. Commun., 2000,0, 2187-2188
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    Synthesis and crystal structure of [IBa(OBut)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium

    K. M. Fromm, E. D. Gueneau and H. Goesmann, Chem. Commun., 2000, 0, 2187
    DOI: 10.1039/B005638N

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