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Issue 19, 2000
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Amavadine as a catalyst for the peroxidative halogenation, hydroxylation and oxygenation of alkanes and benzene

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Abstract

Synthetic amavadine models, [V(HIDPA)2]2− and [V(HIDA)2]2− [where HIDPA and HIDA stand for the basic forms of 2,2′-(hydroxyimino)dipropionic and 2,2′-(hydroxyimino)diacetic acid, respectively], exhibit haloperoxidase- or peroxidase-type activities, and act as catalysts for the selective peroxidative monohalogenation, hydroxylation or oxo-functionalization of alkanes or aromatic compounds such as benzene and mesitylene at room temperature.

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Publication details

The article was received on 10 Jul 2000, accepted on 31 Jul 2000 and first published on 14 Sep 2000


Article type: Communication
DOI: 10.1039/B005513L
Citation: Chem. Commun., 2000,0, 1845-1846
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    Amavadine as a catalyst for the peroxidative halogenation, hydroxylation and oxygenation of alkanes and benzene

    P. M. Reis, J. Armando, L. Silva, J. J. R. F. da Silva and A. J. L. Pombeiro, Chem. Commun., 2000, 0, 1845
    DOI: 10.1039/B005513L

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