Highly Z-selective synthesis of α,β-unsaturated amides with the Peterson reaction between α-silylamides and aldehydes
The Peterson reaction of triphenylsilylacetamide Ph3SiCH2CONBn2 with aromatic aldehydes and certain aliphatic aldehydes proceeded to give the corresponding α,β-unsaturated amide with high Z selectivity (up to Z∶E = >97∶<3).
The article was received on 02 Jun 2000, accepted on 03 Aug 2000 and first published on 04 Sep 2000
Highly Z-selective synthesis of α,β-unsaturated amides with the Peterson reaction between α-silylamides and aldehydes
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