Möbius aromatics arising from a CCC ring component

Sonsoles Martín-Santamaría; Balasundaram Lavan; Henry S. Rzepa

doi:10.1039/B002462G

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Chemical Communications

Issue 12, 2000

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Möbius aromatics arising from a CCC ring component

Sonsoles Martín-Santamaría , Balasundaram Lavan and Henry S. Rzepa

Chem. Commun., 2000, 1089-1090

DOI: 10.1039/B002462G
Received 28 Mar 2000, Accepted 02 May 2000
First published on the web 01 Jun 2000

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Abstract
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Replacement of one planar C [double bond, length half m-dash] C unit in Hückel 4n + 2 aromatic rings by a twisted CCC results in chiral 4n π Möbius aromatic rings.

Supplementary Info

AM1 allene orbitals (Fig. 1)
DOC (202K)
Computed 3D coordinates (PDB files) and selected orbitals (3DMF files) for 1– 21
HTM (14K)

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Chemical Communications

Möbius aromatics arising from a CCC ring component

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