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Issue 7, 2000
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Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(III) complex

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Abstract

Excellent enantioselectivity (e.g. 92% ee for 2,2-dimethylchromene) has been achieved in heterogeneous asymmetric epoxidation using a polymer-bound (pyrrolidine salen)-manganese(III) complex; however, this polymeric catalyst underwent partial decomposition under epoxidation conditions.

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Publication details

The article was received on 01 Feb 2000, accepted on 06 Mar 2000 and first published on 22 Mar 2000


Article type: Communication
DOI: 10.1039/B000876L
Citation: Chem. Commun., 2000,0, 615-616
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    Heterogeneous asymmetric epoxidation of alkenes catalysed by a polymer-bound (pyrrolidine salen)manganese(III) complex

    C. E. Song, E. J. Roh, B. M. Yu, D. Y. Chi, S. C. Kim and K. Lee, Chem. Commun., 2000, 0, 615
    DOI: 10.1039/B000876L

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