Issue 7, 2000

The hydroxylation and amidation of equilenin acetate catalyzed by chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(iii)

Abstract

The aromatic steroid equilenin acetate undergoes regioselective and stereoselective hydroxylation and amidation catalyzed by a manganese porphyrin using iodosobenzene (PhIO) and N-tosyliminophenyliodinane (PhINTs) as the oxygen and nitrogen donor, respectively.

Article information

Article type
Communication
Submitted
11 Jan 2000
Accepted
14 Feb 2000
First published
13 Mar 2000

Chem. Commun., 2000, 531-532

The hydroxylation and amidation of equilenin acetate catalyzed by chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(III)

J. Yang, R. Weinberg and R. Breslow, Chem. Commun., 2000, 531 DOI: 10.1039/B000463O

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