Issue 1, 2000

Photo-induced tautomerisation of methyltrioxorhenium(vii): the intermediate in olefin metathesis?

Abstract

Matrix-isolated [CH3ReO3] tautomerises to [H2C[double bond, length half m-dash]Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

Article information

Article type
Feature Article
Submitted
28 Sep 1999
Accepted
01 Dec 1999
First published
07 Jan 2000

Chem. Commun., 2000, 67-68

Photo-induced tautomerisation of methyltrioxorhenium(VII): the intermediate in olefin metathesis?

L. J. Morris, A. J. Downs, T. M. Greene, G. S. McGrady, W. A. Herrmann, P. Sirsch, O. Gropen and W. Scherer, Chem. Commun., 2000, 67 DOI: 10.1039/A907908D

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