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Issue 1, 2000
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Photo-induced tautomerisation ofmethyltrioxorhenium(VII): the intermediate in olefinmetathesis?

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Abstract

Matrix-isolated [CH3ReO3] tautomerises to [H2C[double bond, length half m-dash]Re(O)2OH] under the influence of UV light; the carbene has been characterised in its normal and 2H- and 13C-enriched isotopic forms by its IR spectrum with results well replicated by quantum chemical calculations.

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Publication details

The article was received on 28 Sep 1999, accepted on 01 Dec 1999 and first published on 07 Jan 2000


Article type: Feature Article
DOI: 10.1039/A907908D
Citation: Chem. Commun., 2000,0, 67-68
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    Photo-induced tautomerisation of methyltrioxorhenium(VII): the intermediate in olefin metathesis?

    L. J. Morris, A. J. Downs, T. M. Greene, G. S. McGrady, W. A. Herrmann, P. Sirsch, O. Gropen and W. Scherer, Chem. Commun., 2000, 0, 67
    DOI: 10.1039/A907908D

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