Issue 24, 2000
From the journal:

Chemical Communications

[Pt2(GaCp*)2(μ2-Ga Cp*)3]: structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

Dana Weiß,a   Manuela Winter,a   Roland A. Fischer,*a   Chen Yu,b   Karin Wichmannb  and  Gernot Frenking*b  

* Corresponding authors

a Lehrstuhl für Anorganische Chemie II, Organometallics & Materials Chemistry, Ruhr-Universität Bochum, Universitätsstraße 150, Bochum, Germany.
E-mail: rfischer@aci.ruhr-uni-bochum.de

b Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, Marburg, Germany.
E-mail: frenking@chemie.uni-marburg.de

Abstract

A new homoleptic diplatinum complex [Pt2(GaCp*)2(μ2-GaCp*)3] (Cp* = pentamethylcyclopentadienyl) exhibiting a central unit of two platinum atoms coordinated by five Cp*Ga groups acting as terminal as well as bridging ligands, was synthesized by the reaction of tris(ethylene)platinum(0) with an excess of (Cp*Ga)6 and was characterized by structural and quantum chemical methods.

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Article information

DOI
https://doi.org/10.1039/B008133G
Article type
Communication
Submitted
09 Oct 2000
Accepted
30 Oct 2000
First published
30 Nov 2000

Chem. Commun., 2000, 2495-2496

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[Pt2(GaCp*)2(μ2-Ga Cp*)3]: structure and bonding situation of the first homoleptic platinum complex with terminal and bridging Cp*Ga ligands

D. Weiß, M. Winter, R. A. Fischer, C. Yu, K. Wichmann and G. Frenking, Chem. Commun., 2000, 2495 DOI: 10.1039/B008133G

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