Issue 10, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides

Gilles Guerrero,   Michael Mehring,   P. Hubert Mutin,   Françoise Dahan  and  André Vioux  

Abstract

The reactions of PhP(O)(OH)2 or Ph2P(O)OH with Ti(OPri)4 in DMSO give the soluble tetranuclear complexes [Ti4(µ3-O)(OPri)5(µ-OPri)3(PhPO3)3]·DMSO 1 or [Ti(µ3-O)(OPri)(Ph2PO2)]4·0.5DMSO 2, the first examples of phosphonato- and phosphinato-bridged titanium oxo alkoxides, which have been characterised by single-crystal X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/A902407G
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 1537-1538

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Syntheses and single-crystal structures of novel soluble phosphonato- and phosphinato-bridged titanium oxo alkoxides

G. Guerrero, M. Mehring, P. Hubert Mutin, F. Dahan and A. Vioux, J. Chem. Soc., Dalton Trans., 1999, 1537 DOI: 10.1039/A902407G

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