Jump to main content
Jump to site search

Issue 2, 1999
Previous Article Next Article

Observation of a cubic phase in mesoporous silicate films grown at the air/water interface

Abstract

X-Ray diffraction is reported from mesoporous silicate films grown at the air/water interface. The films were studied both as powdered films, and oriented on silicon or mica sheets. At early stages of growth we observe Bragg diffraction from a highly ordered cubic phase, with both long and short d-spacing peaks. We have assigned this as a discontinuous micellar Pm3n phase in which the silica is partly ordered. Later films retain only the known hexagonal p6m peaks and have lost any order both at short d-spacings and the longer d-spacing Bragg peaks characteristic of the cubic structure. The silica framework is considerably expanded from that in bulk amorphous silica, average Si···Si distances are some 30% greater. Incorporation of glycerol or polyethylene glycol preserves the earlier cubic structure. To be consistent with earlier, insitu, X-ray and neutron reflectivity data we infer that both structures are produced after a phase transition from a less-ordered film structure late in the induction phase. The structural relations between the film Pm3n and p6m phase(s) and the known bulk SBA-1 and MCM-41 phases are briefly discussed.

Back to tab navigation

Article type: Paper
DOI: 10.1039/A807840H
Citation: Phys. Chem. Chem. Phys., 1999,1, 323-328
  •   Request permissions

    Observation of a cubic phase in mesoporous silicate films grown at the air/water interface

    J. L. Ruggles, S. A. Holt, P. A. Reynolds, A. S. Brown, D. C. Creagh and J. W. White, Phys. Chem. Chem. Phys., 1999, 1, 323
    DOI: 10.1039/A807840H

Search articles by author

Spotlight

Advertisements