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The crystal molecular structure of a model peptide, Boc-Ile-Thr-NH2, unexpectedly revealed two unusual intramolecularly hydrogen bonded ring motifs, i.e. an intraresidue main-chain to main-chain interaction (Ni–H‥O![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
Ci) and an interresidue ‘newly discovered’ side-chain to main-chain interaction (Ni–H‥OiγThr), across a polar proteinogenic residue.
A. K. Thakur, A. R. K. and R. Kishore, Chem. Commun., 1999, 1643 DOI: 10.1039/A904711E
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