Physisorption of oxygen in narrow mesopores

Peter J. Branton; Katsumi Kaneko; Kenneth S. W. Sing

doi:10.1039/A900795D

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Chemical Communications

Issue 7, 1999

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Physisorption of oxygen in narrow mesopores

Peter J. Branton , Katsumi Kaneko and Kenneth S. W. Sing

Chem. Commun., 1999, 575-576

DOI: 10.1039/A900795D

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Pore filling by oxygen takes place reversibly at 77 K in pores of effective width of ca. 2.6 nm, whereas hysteresis is involved in the filling (by capillary condensation) of wider pores; it appears that the oxygen meniscus becomes unstable at cylindrical pore widths < ca. 2.9 nm.

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Chemical Communications

Physisorption of oxygen in narrow mesopores

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