Issue 5, 1999

Rate constants for the reaction of cumylperoxyl radicals with Bu3SnH and (TMS)3SiH

Abstract

The rate constants for the reaction of a cumylperoxyl radical with Bu3SnH and (TMS)3SiH were determined at 72.5 °C to be 1600 and 66 M–1 s–1, respectively, by using inhibited hydrocarbon oxidation methodologies.

Article information

Article type
Paper

Chem. Commun., 1999, 405-406

Rate constants for the reaction of cumylperoxyl radicals with Bu3SnH and (TMS)3SiH

C. Chatgilialoglu, V. I. Timokhin, A. B. Zaborovskiy, D. S. Lutsyk and R. E. Prystansky, Chem. Commun., 1999, 405 DOI: 10.1039/A808894B

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