Linear dimerisation of but-1-ene in biphasic mode using buffered chloroaluminate ionic liquid solvents

B. Ellis; W. Keim; P. Wasserscheid

doi:10.1039/A808346K

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Chemical Communications

Issue 4, 1999

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Paper

Linear dimerisation of but-1-ene in biphasic mode using buffered chloroaluminate ionic liquid solvents

B. Ellis, W. Keim and P. Wasserscheid

Chem. Commun., 1999, 337-338

DOI: 10.1039/A808346K

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Abstract
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The use of a buffered ionic liquid as a solvent for catalysts known to produce linear dimers from but-1-ene has been explored; this resulted in a significant enhancement of the activity of known catalysts, combined with the retention of both dimer selectivity and product linearity; in addition, the biphasic mode of operation allows easy catalyst recovery and recycle.