The complex [Au(acetonine)2]ClO4 (3·ClO4) (acetonine = 2,2,4,4,6-pentamethyl-2,3,4,5-tetrahydropyrimidine) is obtained by bubbling NH3 through an acetone solution containing equimolar amounts of NaClO4 and [AuCl(tht)] (tht = tetrahydrothiophene); the crystal structure of 3·ClO4 was determined by X-ray crystallography.
J. Vicente, M. Teresa Chicote, R. Guerrero and M. Carmen Ramírez de Arellano, Chem. Commun., 1999, 1541 DOI: 10.1039/A904777H
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