Issue 16, 1999

Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments

Abstract

Treatment of η1-[1,3-bis(diisopropylamino)-1H-diphosphirene]tetracarbonyl iron 2 with trifluoromethanesulfonic acid affords the binuclear [3-diisopropylaminodiphosphirenylium salt] iron complex 5, which reacts with diisopropylamine giving the opened binuclear iron complex 3.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 1535-1536

Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments

D. Bourissou, Y. Canac, H. Gornitzka, A. Baceiredo and G. Bertrand, Chem. Commun., 1999, 1535 DOI: 10.1039/A904747F

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