The reaction of meso-octaethylporphyrinogen–lanthanide complexes, [{(η5∶η1∶η5∶η1-Et8N4)M}Na(thf)2] [M = Pr, Nd], with NaC10H8 in an ethylene or acetylene atmosphere leads to the isolation of dimeric species, where the metals are bridged by the [C2H4]2– and [C2]2– anions.
E. Campazzi, E. Solari, R. Scopelliti and C. Floriani, Chem. Commun., 1999, 1617 DOI: 10.1039/A904032C
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