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Issue 16, 1999
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Synthesis and characterization of ‘calixsalens’: a new class of macrocyclic chiral ligands

Abstract

Template directed reaction of dialdehydes and (R,R)- or (S,S)-1,2-diaminocyclohexane affords a practical route to chiral, metal-free macrocyclic salen dimers which have a novel calixarene-like structure and show catalytic activity for enantioselective epoxidation of unfunctionalized alkenes in the presence of MnIII–NaOCl (aq.).

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Article type: Paper
DOI: 10.1039/A900018F
Citation: Chem. Commun., 1999, 1531-1532
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    Synthesis and characterization of ‘calixsalens’: a new class of macrocyclic chiral ligands

    Z. Li and C. Jablonski, Chem. Commun., 1999, 1531
    DOI: 10.1039/A900018F

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