A new CuI(SCN) structural motif: synthesis of an uncharged three-dimensional co-ordination network

Alexander J. Blake; Neil R. Champness; Marcello Crew; Lyall R. Hanton; Simon Parsons; Martin Schröder

doi:10.1039/A801241E

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Journal of the Chemical Society, Dalton Transactions

Issue 10, 1998

The international journal for inorganic, organometallic and bioinorganic chemistry

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Paper

A new Cu^I(SCN) structural motif: synthesis of an uncharged three-dimensional co-ordination network

Alexander J. Blake, Neil R. Champness, Marcello Crew, Lyall R. Hanton, Simon Parsons and Martin Schröder

J. Chem. Soc., Dalton Trans., 1998, 1533-1534

DOI: 10.1039/A801241E

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Abstract
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The complex [Cu₂(SCN)₂(L)]_∞ (L = pyrazine) has been prepared and characterised by X-ray diffraction studies revealing a new uncharged three-dimensional co-ordination network consisting of undulating [Cu(SCN)]_∞ sheets bridged by pyrazine ligands.