Successive protonation of [Fe4S4(SPh)4]2– progressively labilises the cluster towards substitution of the thiolate ligands, whereas single protonation of [Fe4S4Cl4]2– catalyses, but diprotonation inhibits, substitution of the chloro-ligands.
R. A. Henderson and K. E. Oglieve, J. Chem. Soc., Dalton Trans., 1998, 1731 DOI: 10.1039/A802303D
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