Issue 21, 1998

Facile oxidation of a carbaporphyrin at the internal carbon atom: synthesis of novel benzo[18]annulene ketals†

Abstract

Treatment of benzocarbaporphyrin 2 with refluxing FeCl3 in CHCl3–alcohol mixtures leads to a remarkably selective oxidation at the interior carbon atom to produce dialkoxy products 5; these species show potentially valuable long wavelength absorptions in their UV–VIS spectra.

Article information

Article type
Paper

Chem. Commun., 1998, 2409-2410

Facile oxidation of a carbaporphyrin at the internal carbon atom: synthesis of novel benzo[18]annulene ketals†

M. J. Hayes, J. D. Spence and T. D. Lash, Chem. Commun., 1998, 2409 DOI: 10.1039/A806394J

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