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The crystal structure of an anionic azo dye rotaxane shows that the cyclophane embraces the centre of the dye; sodium coordinates to both the dye and the cyclophane, as well as DMSO solvent molecules, resulting in an infinite polyrotaxane network.
S. Anderson, H. L. Anderson and W. Clegg, Chem. Commun., 1998, 2379 DOI: 10.1039/A805649H
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