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Issue 18, 1998
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Synthesis of oligomers of tetrahydrofuran amino acids: furanose carbopeptoids

Abstract

An acid catalysed ring rearrangement of a triflate derivative of D-mannono-?-lactone 6 is the key step in the synthesis of the C-glycosyl sugar amino acid derivatives 3 and 4, examples of carbohydrate amino acid building blocks with specific conformational preferences suitable for incorporation into combinatorial amide libraries; homo-oligomerisation via solution phase coupling procedures affords furanose carbopeptoids 1 which adopt novel solution state secondary structures.

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Article type: Paper
DOI: 10.1039/A805364B
Citation: Chem. Commun., 1998,0, 2039-2040
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    Synthesis of oligomers of tetrahydrofuran amino acids: furanose carbopeptoids

    M. D. Smith, D. D. Long, T. D. W. Claridge, G. W. J. Fleet, D. G. Marquess and D. G. Marquess, Chem. Commun., 1998, 0, 2039
    DOI: 10.1039/A805364B

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