New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo[7.5.1.01,6.06,13.08,12.010,14]pentadeca-2,4-diene system

Goverdhan Mehta; R. Uma; M. N. Jagadeesh; Jayaraman Chandrasekhar

doi:10.1039/A804313B

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Chemical Communications

Issue 17, 1998

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New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo[7.5.1.0^1,6.0^6,13.0^8,12.0^10,14]pentadeca-2,4-diene system

Goverdhan Mehta , R. Uma , M. N. Jagadeesh and Jayaraman Chandrasekhar

Chem. Commun., 1998, 1813-1814

DOI: 10.1039/A804313B

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Different modes of direct through-space interactions between remote substituents and an approaching reagent are indicated as important additional controlling factors of face selectivity in singlet oxygen cycloaddition to facially differentiated cyclohexa-1,3-dienes.

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Chemical Communications

New paradigms in cycloaddition face-selectivities: remarkable effect of remote substituents in singlet oxygen addition to hexacyclo[7.5.1.0^1,6.0^6,13.0^8,12.0^10,14]pentadeca-2,4-diene system

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