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Issue 15, 1998
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‘Phospha-Wittig’ reactions using isolable phosphoranylidenephosphines ArP[double bond, length half m-dash]PR3 (Ar = 2,6-Mes2C6H3 or 2,4,6-But3C6H2)

Abstract

Phosphoranylidenephosphines DmpP[double bond, length half m-dash]PMe3 (1a, Dmp = 2,6-Mes2C6H3) and Mes*P[double bond, length half m-dash]PMe3 (1b, Mes* = 2,4,6-But3C6H2) act as ‘Phospha-Wittig’ reagents with aldehydes providing phosphaalkenes [ArP[double bond, length half m-dash]C(H)R] in high yields.

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Article type: Paper
DOI: 10.1039/A802722F
Citation: Chem. Commun., 1998,0, 1585-1586
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    ‘Phospha-Wittig’ reactions using isolable phosphoranylidenephosphines ArP[double bond, length half m-dash]PR3 (Ar = 2,6-Mes2C6H3 or 2,4,6-But3C6H2)

    S. Shah and J. D. Protasiewicz, Chem. Commun., 1998, 0, 1585
    DOI: 10.1039/A802722F

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