Issue 12, 1998

Ln2□Ti2O7 (Ln = La, Nd, Sm, Gd): a novel series of defective Ruddlesden–Popper phases formed by topotactic dehydration of HLnTiO4+

Abstract

Topotactic dehydration of HLnTiO4 (Ln = La, Nd, Sm or Gd) around 480–500 °C yields a new series of metastable layered perovskite oxides, Ln2□Ti2O7, that possess a defective Sr3Ti2O7 structure, where the cubooctahedral sites within the double-perovskite layers are most likely vacant.

Article information

Article type
Paper

Chem. Commun., 1998, 1299-1300

Ln2□Ti2O7 (Ln = La, Nd, Sm, Gd): a novel series of defective Ruddlesden–Popper phases formed by topotactic dehydration of HLnTiO4+

V. Thangadurai, J. Gopalakrishnan and G. N. Subbanna, Chem. Commun., 1998, 1299 DOI: 10.1039/A802644K

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