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Issue 8, 1998
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Synthesis, crystal and molecular structure of the first indium trihydride complex, [InH3{C[upper bond 1 start]N(Pri)C2Me2N[upper bond 1 end](Pri)}]

Abstract

The reaction of either [InH3(NMe3)] or LiInH4 with an excess of the imidazol-2-ylidene carbene, :C[upper bond 1 start]N(Pri)C2Me2N[upper bond 1 end](Pri), affords the first example of an indium trihydride complex, [InH3{C[upper bond 1 start]N(Pri)C2Me2N[upper bond 1 end](Pri)}], the X-ray crystal structure of which is described.

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Article type: Paper
DOI: 10.1039/A801118D
Citation: Chem. Commun., 1998,0, 869-870
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    Synthesis, crystal and molecular structure of the first indium trihydride complex, [InH3{C[upper bond 1 start]N(Pri)C2Me2N[upper bond 1 end](Pri)}]

    D. E. Hibbs, M. B. Hursthouse, M. B. Hursthouse, C. Jones and N. A. Smithies, Chem. Commun., 1998, 0, 869
    DOI: 10.1039/A801118D

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