Structural dependence of the reagent Ph3PCl2 on the nature of the solvent, both in the solid state and in solution; X-ray crystal structure of trigonal bipyramidal Ph3PCl2, the first structurally characterised five-coordinate R3PCl2 compound

Stephen M. Godfrey; Charles A. McAuliffe; Joanne M. Sheffield

doi:10.1039/A800820E

This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Communications > Structural dependence o...

For Authors & Referees | For Librarians | For Members

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Communications

Issue 8, 1998

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

Journal Home

Previous Article | Next Article

Paper

Structural dependence of the reagent Ph₃PCl₂ on the nature of the solvent, both in the solid state and in solution; X-ray crystal structure of trigonal bipyramidal Ph₃PCl₂, the first structurally characterised five-coordinate R₃PCl₂ compound

Stephen M. Godfrey, Charles A. McAuliffe and Joanne M. Sheffield

Chem. Commun., 1998, 921-922

DOI: 10.1039/A800820E

Please wait while Download options loads

Download Citation

Request Permissions

Abstract
Cited by
Related Content

The very delicate structural balance of Ph₃PCl₂ when prepared in diethyl ether solution is illustrated by its X-ray crystallographic study; unlike the ionic species, [Ph₃PCl⁺···Cl^–···⁺ClPPh₃]Cl, which prevails in dichloromethane solution, the non-solvated molecular species Ph₃PCl₂ is formed in diethyl ether which is the first example of a trigonal bipyramidal R₃PCl₂ compound to be structurally characterised, and this may have an effect on the chlorinating ability of the reagent.

Chemical Communications - Information Point

About this Journal

People and Contacts

Submit to this Journal

Editorial Board

Authors and Referees

Subscription Information

Follow Journal | |

Terms & Conditions|Privacy and Cookies |Accessibility|ACAP Enabled

Chemical Communications

Structural dependence of the reagent Ph₃PCl₂ on the nature of the solvent, both in the solid state and in solution; X-ray crystal structure of trigonal bipyramidal Ph₃PCl₂, the first structurally characterised five-coordinate R₃PCl₂ compound

Log in (Free Access)

Log in (Subscriber Access)

Search Articles By

Chemical Communications

Structural dependence of the reagent Ph3PCl2 on the nature of the solvent, both in the solid state and in solution; X-ray crystal structure of trigonal bipyramidal Ph3PCl2, the first structurally characterised five-coordinate R3PCl2 compound

This text is added as a work around for heading error in Accessibility testing

Log in (Free Access)

Log in (Subscriber Access)

Search Articles By

Structural dependence of the reagent Ph₃PCl₂ on the nature of the solvent, both in the solid state and in solution; X-ray crystal structure of trigonal bipyramidal Ph₃PCl₂, the first structurally characterised five-coordinate R₃PCl₂ compound