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Issue 3, 1998
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Synthesis and characterization of Ag2C2·2AgClO4·2H2O: a novel layer-type structure with the acetylide dianion functioning in a µ6112222 bonding mode inside an octahedral silver cage

Abstract

In the novel double salt Ag2C2·2AgClO4·2H2O, the C22– dianion [bond length 1.217(7) Å] is encapsulated inside an octahedral Ag6 cage, and the resulting cationic [C2@Ag6] units share corners to generate metallic layers between which the perchlorate anions and aqua ligands are accommodated.

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Article type: Paper
DOI: 10.1039/A708439K
Citation: Chem. Commun., 1998, 339-340
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    Synthesis and characterization of Ag2C2·2AgClO4·2H2O: a novel layer-type structure with the acetylide dianion functioning in a µ6112222 bonding mode inside an octahedral silver cage

    G. Guo, Chem. Commun., 1998, 339
    DOI: 10.1039/A708439K

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