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Issue 5, 1998
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New insights into the formation of extended supramolecular architectures from simple building blocks

Abstract

Reaction of uranyl acetate with HCl and 15-crown-5 in toluene results in the formation of a liquid clathrate phase from which crystals of (H5O2)[UO2Cl3(H2O)2]·(15-crown-5)2 1 are deposited; on standing, loss of HCl results in the isolation of a second product [UO2Cl2(H2O)3]16·(15-crown-5)16 2 which displays an extremely complex hydrogen bonded chain structure in the solid state.

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Article type: Paper
DOI: 10.1039/A707744K
Citation: Chem. Commun., 1998,0, 577-578
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    New insights into the formation of extended supramolecular architectures from simple building blocks

    H. Hassaballa, J. W. Steed and P. C. Junk, Chem. Commun., 1998, 0, 577
    DOI: 10.1039/A707744K

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