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Issue 18, 1998
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A highly ordered ferrocene system regulated by podand peptide chains

Abstract

The ferrocene bearing the podand dipeptide chains, Ala-Pro-OEt, which are aligned parallel in solution by the two rigid intramolecular hydrogen bonds, manifests a novel helically ordered arrangement with one turn of 14.70 Å pitch height in the crystal packing possibly due to the intramolecular hydrogen bonds (the N–H···O[double bond, length half m-dash]C distance is 2.06 Å) and the hydrophobic interaction of the podand dipeptide chains (the distance between the nearest ferrocene units is 4.54 Å).

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Article type: Paper
DOI: 10.1039/A805780J
Citation: Chem. Commun., 1998, 1963-1964
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    A highly ordered ferrocene system regulated by podand peptide chains

    A. Nomoto, T. Moriuchi, S. Yamazaki, A. Ogawa and T. Hirao, Chem. Commun., 1998, 1963
    DOI: 10.1039/A805780J

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