Certain carbon and sulfur nucleophiles add to the β-terminus of the styrene system in α,β-unsaturated arene ruthenium(II) cyclopentadiene complexes, and unexpected endo addition occurs preferentially in some cases.
R. M. Moriarty, L. A. Enache, G. L. Gould, D. J. Wink, L. A. Enache and R. Gilardi, Chem. Commun., 1998, 1155 DOI: 10.1039/A707386K
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