A new type of metal sandwich structure [Ag{[Au(µ-N3,C2- bzim)]3}2]BF4·CH2Cl2 1, is formed by reacting the neutral, triangular cluster [Au(µ-N3,C2-bzim)]3 with Ag+; these units stack with two short intermolecular Au···Au distances of ca. 3.2 Å.
A. Burini, R. Galassi, B. R. Pietroni, A. Burini, J. P. Fackler Jr., R. Galassi and R. J. Staples, Chem. Commun., 1998, 95 DOI: 10.1039/A706795J
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