Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

Adusumilli Srikrishna; Dange Vijaykumar

doi:10.1039/A705600A

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Journal of the Chemical Society, Perkin Transactions 1

Issue 22, 1997

Perkin Transactions 1 ceased publication in 2002. Organic & Biomolecular Chemistry is the RSC's journal for high-quality, original organic chemistry research.

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Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

Adusumilli Srikrishna and Dange Vijaykumar

J. Chem. Soc., Perkin Trans. 1, 1997, 3295-3296

DOI: 10.1039/A705600A

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Abstract
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Total synthesis of (±)-α-pinguisene 1 and (±)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.

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Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

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Journal of the Chemical Society, Perkin Transactions 1

Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

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