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Issue 22, 1997
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Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

Abstract

Total synthesis of (±)-α-pinguisene 1 and (±)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.

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Article type: Paper
DOI: 10.1039/A705600A
Citation: J. Chem. Soc., Perkin Trans. 1, 1997,0, 3295-3296
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    Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

    A. Srikrishna and D. Vijaykumar, J. Chem. Soc., Perkin Trans. 1, 1997, 0, 3295
    DOI: 10.1039/A705600A

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