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Issue 10, 1997
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Inclusion and separation of picoline isomers by a diol host compound

Mino R. Caira,  Alicia Horne,  Luigi R. Nassimbeni  and  Fumio Toda 

Abstract

Structures of the inclusion compounds formed between the host compound 1,1-bis(4-hydroxyphenyl)cyclohexane and the isomers of picoline have been elucidated. The activation energies and the kinetics of desolvation for the complexes have been determined. Competition experiments have been performed to investigate which isomer is preferentially enclathrated by the host. Lattice energy calculations explain the results of the competition experiments.

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Article type: Paper
DOI: 10.1039/A703221H
Citation: J. Mater. Chem., 1997,7, 2145-2149
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    Inclusion and separation of picoline isomers by a diol host compound

    M. R. Caira, A. Horne, L. R. Nassimbeni and F. Toda, J. Mater. Chem., 1997, 7, 2145
    DOI: 10.1039/A703221H

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