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Issue 3, 1997
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Crystal structures and electronic properties ofUTixNb3-xO10 (x=0,1/3,1)and of the intercalation compoundLi0.9UTiNb2O10

Abstract

Complete crystal structures of the related phases UTi x Nb 3-x O 10 (x=0,1/3,1) and of the intercalation compound Li 0.9 UTiNb 2 O 10 have been determined by Rietveld analysis of room-temperature powder neutron diffraction data. The new structural data combined with magnetic susceptibility measurements made in the range 5<T/K<300 support a common electronic formulation of the compounds as Li I y U V 1+y -x U VI x-y Ti IV x Nb V 3-x O 10 ( y≤x≤1) with U V (f 1 ) being the only paramagnetic species present.

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Article type: Paper
DOI: 10.1039/A605883C
Citation: J. Mater. Chem., 1997,7, 537-543
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    Crystal structures and electronic properties of UTixNb3-xO10 (x=0,1/3,1) and of the intercalation compound Li0.9UTiNb2O10

    Peter G. Dickens, G. J. Flynn, S. Patat and Gary P. Stuttart, J. Mater. Chem., 1997, 7, 537
    DOI: 10.1039/A605883C

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