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Issue 17, 1997
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X-Ray diffraction from layers of n-alkanes adsorbed on graphite

Philippe Espeau,  Philip A. Reynolds,  Trevor Dowling,  David Cookson  and  John W. White 

Abstract

The structure of 1 to 80 layers of C 16 H 34 and C 17 H 36 n-alkanes adsorbed on graphite has been studied as a function of temperature using synchrotron X-ray radiation. The measurements confirm that a surface phase of two to four layers, distinct from the bulk adsorbed on the graphite, is formed at room temperature. The structure of the subsequent layers, for a particular hydrocarbon, is not appreciably affected by the number of layers. Warren-like peaks are observed for the adsorbed phase and can be indexed in a centred oblique two-dimensional lattice.

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Article type: Paper
DOI: 10.1039/A701071K
Citation: J. Chem. Soc., Faraday Trans., 1997,93, 3201-3208
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    X-Ray diffraction from layers of n-alkanes adsorbed on graphite

    P. Espeau, P. A. Reynolds, T. Dowling, D. Cookson and J. W. White, J. Chem. Soc., Faraday Trans., 1997, 93, 3201
    DOI: 10.1039/A701071K

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