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Issue 9, 1997
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Collisions of Fe+ ions, clusters and hydroxidesligated by water molecules

P. Pradel,  L. Poisson,  J. P. Visticot,  J. M. Mestdagh  and  C. Rolando 

Abstract

A laser evaporation source has been used to generate a beam of Fe + , FeOH + , Fe(OH) 2 + , FeH + , Fe 2 + and Fe 3 + ions solvated by up to 11 water molecules, with the major series of ions corresponding to Fe(H 2 O) n + clusters. These ions were collided, prior to mass selection, with Ar, N 2 , O 2 or CH 3 OH, and apparent scattering cross-sections were measured. Simple collision models, coupled with a Monte Carlo simulation of the scattering experiment, were used to account quantitatively for the observations. The most striking result is that only methanol exchanges with a cluster water molecule, although this is a minor channel. There is inelastic scattering with argon but the other collisions are mainly elastic.

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Article type: Paper
DOI: 10.1039/A605415C
Citation: J. Chem. Soc., Faraday Trans., 1997,93, 1697-1703
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    Collisions of Fe+ ions, clusters and hydroxides ligated by water molecules

    P. Pradel, L. Poisson, J. P. Visticot, J. M. Mestdagh and C. Rolando, J. Chem. Soc., Faraday Trans., 1997, 93, 1697
    DOI: 10.1039/A605415C

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