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Issue 9, 1997
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The reactivity of [2.2.2]paracyclophane towardsCr(CO)6: experimental and theoretical considerations

Abstract

The reactivity of [2.2.2]paracyclophane (C 24 H 24 ) towards hexacarbonylchromium has been examined and the rates of reaction for the formation of mono-, bis- and tris-complexes established. The structures of [Cr(CO) 3 (η-C 24 H 24 )] and [{Cr(CO) 3 } 2 (η-C 24 H 24 )] have been established by single crystal X-ray diffraction. These experimental observations have been interpreted using approximate density functional molecular orbital calculations.

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Article type: Paper
DOI: 10.1039/A700484B
Citation: J. Chem. Soc., Dalton Trans., 1997,0, 1601-1606
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    The reactivity of [2.2.2]paracyclophane towards Cr(CO)6: experimental and theoretical considerations

    P. J. Dyson, D. G. Humphrey, J. E. McGrady, P. Suman and D. Tocher, J. Chem. Soc., Dalton Trans., 1997, 0, 1601
    DOI: 10.1039/A700484B

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