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Issue 24, 1997
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Synthesis of the naturally occurring [3.3.3]propellane (±)-modhephene featuring a photocycloaddition–reductive fragmentation diquinane construction

Abstract

Modhephene has been synthesized in 11 steps and 21% overall yield from cyclopentadiene, by a stereoselective route that features a photocycloaddition–fragmentation sequence for the construction of the diquinane core.

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Article type: Paper
DOI: 10.1039/A704260D
Citation: Chem. Commun., 1997,0, 2381-2382
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    Synthesis of the naturally occurring [3.3.3]propellane (±)-modhephene featuring a photocycloaddition–reductive fragmentation diquinane construction

    C. A. Dvorak and V. H. Rawal, Chem. Commun., 1997, 0, 2381
    DOI: 10.1039/A704260D

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