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Issue 20, 1997
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A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation

Abstract

Carbon monoxide is lost upon sodium amalgam reduction of [(OCN)Nb{N(R)Ar}3] [R = C(CD3)2CH3, Ar = C6H3Me2-3,5] to give crystallographically characterized [Na{NNb- [N(R)Ar]3}]2, a nucleophilic niobium(V) nitride which reacts with ClP(NMe2)2 and O(SO2CF3)2 to give P- and S-substituted imido complexes, respectively.

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Article type: Paper
DOI: 10.1039/A704253A
Citation: Chem. Commun., 1997, 1993-1994
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    A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation

    M. G. Fickes, A. L. Odom and C. C. Cummins, Chem. Commun., 1997, 1993
    DOI: 10.1039/A704253A

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