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Issue 19, 1997
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Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium†

Abstract

All of the Me2NH produced by the reaction of [Sb(NMe2)3] with CyP(H)Li (Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me 1; the complex contains the first example of a group 15 metal phosphinidine anion {[Sb(PR)3]3–}.

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Article type: Paper
DOI: 10.1039/A703979D
Citation: Chem. Commun., 1997, 1879-1880
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    Stoichiometric assembly of [Sb(PCy)3]2Li6·6HNMe2·2C6H5Me; a highly fluxional antimony(III) phosphinidine complex containing Me2NH ligation of lithium†

    M. A. Beswick, J. M. Goodman, A. D. Hopkins, M. A. Paver, P. R. Raithby, A. E. H. Wheatley and D. S. Wright, Chem. Commun., 1997, 1879
    DOI: 10.1039/A703979D

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